http://nextbigfuture.com/
October 25, 2015
Graphene
doped with nitrogen and augmented with cobalt atoms has proven to be an
effective, durable catalyst for the production of hydrogen from water,
according to scientists at Rice University.
The Rice lab of chemist James Tour and colleagues at the Chinese Academy of Sciences, the University of Texas at San Antonio and the University of Houston have reported the development of a robust, solid-state catalyst that shows promise to replace expensive platinum for hydrogen generation.
A
new catalyst just 15 microns thick has proven nearly as effective as
platinum-based
The Rice lab of chemist James Tour and colleagues at the Chinese Academy of Sciences, the University of Texas at San Antonio and the University of Houston have reported the development of a robust, solid-state catalyst that shows promise to replace expensive platinum for hydrogen generation.
catalysts but at a much lower cost, according to
scientists at Rice University. The
catalyst is made of nitrogen-doped
graphene with individual cobalt atoms that activate
the process.
(Credit: Tour Group/Rice University)
Nature Communications - Atomic cobalt on nitrogen-doped graphene for hydrogen generation
Catalysts can split water into its constituent hydrogen and oxygen atoms, a process required for fuel cells. The latest discovery, detailed in Nature Communications, is a significant step toward lower-cost catalysts for energy production, according to the researchers.
“What’s unique about this paper is that we show not the use of metal particles, not the use of metal nanoparticles, but the use of atoms,” Tour said. “The particles doing this chemistry are as small as you can possibly get.”
Even particles on the nanoscale work only at the surface, he said. “There are so many atoms inside the nanoparticle that never do anything. But in our process the atoms driving catalysis have no metal atoms next to them. We’re getting away with very little cobalt to make a catalyst that nearly matches the best platinum catalysts.” In comparison tests, he said the new material nearly matched platinum’s efficiency to begin reacting at a low onset voltage, the amount of electricity it needs to begin separating water into hydrogen and oxygen.
The new catalyst is mixed as a solution and can be reduced to a paper-like material or used as a surface coating. Tour said single-atom catalysts have been realized in liquids, but rarely on a surface. “This way we can build electrodes out of it,” he said. “It should be easy to integrate into devices.”
The researchers discovered that heat-treating graphene oxide and small amounts of cobalt salts in a gaseous environment forced individual cobalt atoms to bind to the material.
Electron microscope images showed cobalt atoms widely dispersed throughout the samples.
They tested nitrogen-doped graphene on its own and found it lacked the ability to kick the catalytic process into gear. But adding cobalt in very small amounts significantly increased its ability to split acidic or basic water.
“This is an extremely high-performance material,” Tour said. He noted platinum-carbon catalysts still boast the lowest onset voltage. “No question, they’re the best. But this is very close to it and much easier to produce and hundreds of times less expensive.”
Atom-thick graphene is the ideal substrate, Tour said, because of its high surface area, stability in harsh operating conditions and high conductivity. Samples of the new catalyst showed a negligible decrease in activity after 10 hours of accelerated degradation studies in the lab.
Abstract
Reduction of water to hydrogen through electrocatalysis holds great promise for clean energy, but its large-scale application relies on the development of inexpensive and efficient catalysts to replace precious platinum catalysts. Here we report an electrocatalyst for hydrogen generation based on very small amounts of cobalt dispersed as individual atoms on nitrogen-doped graphene. This catalyst is robust and highly active in aqueous media with very low overpotentials (30 mV). A variety of analytical techniques and electrochemical measurements suggest that the catalytically active sites are associated with the metal centres coordinated to nitrogen. This unusual atomic constitution of supported metals is suggestive of a new approach to preparing extremely efficient single-atom catalysts.
Nature Communications - Atomic cobalt on nitrogen-doped graphene for hydrogen generation
Catalysts can split water into its constituent hydrogen and oxygen atoms, a process required for fuel cells. The latest discovery, detailed in Nature Communications, is a significant step toward lower-cost catalysts for energy production, according to the researchers.
“What’s unique about this paper is that we show not the use of metal particles, not the use of metal nanoparticles, but the use of atoms,” Tour said. “The particles doing this chemistry are as small as you can possibly get.”
Even particles on the nanoscale work only at the surface, he said. “There are so many atoms inside the nanoparticle that never do anything. But in our process the atoms driving catalysis have no metal atoms next to them. We’re getting away with very little cobalt to make a catalyst that nearly matches the best platinum catalysts.” In comparison tests, he said the new material nearly matched platinum’s efficiency to begin reacting at a low onset voltage, the amount of electricity it needs to begin separating water into hydrogen and oxygen.
The new catalyst is mixed as a solution and can be reduced to a paper-like material or used as a surface coating. Tour said single-atom catalysts have been realized in liquids, but rarely on a surface. “This way we can build electrodes out of it,” he said. “It should be easy to integrate into devices.”
The researchers discovered that heat-treating graphene oxide and small amounts of cobalt salts in a gaseous environment forced individual cobalt atoms to bind to the material.
Electron microscope images showed cobalt atoms widely dispersed throughout the samples.
They tested nitrogen-doped graphene on its own and found it lacked the ability to kick the catalytic process into gear. But adding cobalt in very small amounts significantly increased its ability to split acidic or basic water.
“This is an extremely high-performance material,” Tour said. He noted platinum-carbon catalysts still boast the lowest onset voltage. “No question, they’re the best. But this is very close to it and much easier to produce and hundreds of times less expensive.”
Atom-thick graphene is the ideal substrate, Tour said, because of its high surface area, stability in harsh operating conditions and high conductivity. Samples of the new catalyst showed a negligible decrease in activity after 10 hours of accelerated degradation studies in the lab.
Abstract
Reduction of water to hydrogen through electrocatalysis holds great promise for clean energy, but its large-scale application relies on the development of inexpensive and efficient catalysts to replace precious platinum catalysts. Here we report an electrocatalyst for hydrogen generation based on very small amounts of cobalt dispersed as individual atoms on nitrogen-doped graphene. This catalyst is robust and highly active in aqueous media with very low overpotentials (30 mV). A variety of analytical techniques and electrochemical measurements suggest that the catalytically active sites are associated with the metal centres coordinated to nitrogen. This unusual atomic constitution of supported metals is suggestive of a new approach to preparing extremely efficient single-atom catalysts.
http://www.gizmag.com/
High-efficiency, semi-transparent perovskite/graphene solar cells created at low cost
- Colin Jeffrey
- September 11, 2015
The semi-transparent, inexpensive solar cells have a claimed
conversion efficiency of around 12 percent
(Credit: Hong Kong Polytechnic University)
conversion efficiency of around 12 percent
(Credit: Hong Kong Polytechnic University)
With the continued rise in the uptake of solar cells, consumers are now
looking at less obtrusive ways to incorporate these in buildings and vehicles. Transparent or semi-transparent cells
provide greater flexibility and visual appeal than standard, opaque
silicon solar cells, however their relatively high-cost and poor
efficiencies have meant that their adoption has been slow. To help remedy
this, researchers working at the Hong Kong Polytechnic University
(PolyU) have created semi-transparent, efficient, low-cost perovskite
solar cells with graphene electrodes.
First generation silicon solar cells have been the mainstay of photovoltaic (PV) energy conversion for many years now due to their high stability and efficient energy conversion, but their opacity and expense mean that alternatives are now being actively sought for modern building and vehicle applications. Thin film PVs (second generation solar cells) are lightweight and flexible, but are expensive because they are created from rare materials using complex structures requiring high-temperature production processes.
Now, utilizing such materials as thin-film perovskite, the third generation of solar cell is currently being developed for commercial use in the not-too-distant future with the promise of greater power conversion efficiencies, simpler fabrication processes, and lower cost.
In this vein, the PolyU researchers have developed their own version of the third generation solar cell using semitransparent perovskite with graphene used as the electrodes. Being exceptionally thin but with high conductivity and low cost, graphene makes an ideal choice for semitransparent solar cells as it allows light to be absorbed from both sides. As such, the researchers envisage these devices potentially able to be used in windows, louvers, and building roof surfaces, thereby increasing the available surface area for collecting solar energy.
With a claimed power conversion efficiency of around 12 percent, the PolyU solar cells outperform standard transparent and semi-transparent versions hands-down. The potential to be produced at less than HK $0.50 (US $0.06)/Watt also means a greater than 50 percent saving on the cost of conventional silicon solar cells.
While graphene has been around for more than a decade now and is highly-efficient as a conductor in its own right, the PolyU researchers decided to further enhance the conductivity of graphene to meet their specific requirements. To do this, the graphene was coated with a patina of PEDOT:PSS conductive polymer (poly(3,4-ethylenedioxythiophene) polystyrene sulfonate) – the same ingredient recently used by KAIST scientists in the production of weavable LED fibers – that also acted as an adhesion layer to the perovskite during the process of lamination.
To promote power conversion efficiency, the researchers found that by multilayering graphene through chemical vapor deposition to create transparent electrodes, the sheet resistance of the electrodes was additionally reduced while the exceptional transparency of the electrodes was retained. Finally, the performance of the device was further improved by enhancing the degree of contact between the top graphene electrodes and the hole transport layer on the perovskite film.
According to the researchers, the exceptional flexibility of graphene and the simplified preparation of the cells means that the PolyU device could be eminently suitable for mass production via direct printing or using a roll-to-roll process. In this way, semitransparent solar cells may well provide a greater uptake of PV panels across markets not currently serviced by traditional, opaque devices.
The results of this research were published in the journal Advanced Materials.
Source: Hong Kong Polytechnic University
An
alloy first made nearly two decades ago by the U. S. Navy could provide
an efficient new way to produce electricity. The material, dubbed
Galfenol, consists of iron doped with the metal gallium. In new
experiments, researchers from UCLA, the University of North Texas (UNT),
and the Air Force Research Laboratories have shown that Galfenol can
generate as much as 80 megawatts of instantaneous power per square meter
under strong impacts.
Galfenol converts energy with high efficiency; it is able to turn roughly 70 percent of an applied mechanical energy into magnetic energy, and vice versa. (A standard car, by contrast, converts only about 15 to 30 percent of the stored energy in gasoline into useful motion.) Significantly, the magnetoelastic effect can be used to generate electricity. "If we wrap some wires around the material, we can generate an electrical current in the wire due to a change in magnetization," Domann said.
Galfenol in experiments using a device called a Split-Hopkinson Pressure Bar to generate high amounts of compressive stress (e.g., powerful impacts). They found that when subjected to impacts, Galfenol generates as much as 80 megawatts of instantaneous power per cubic meter.
By way of comparison, a device known as an explosively driven ferromagnetic pulse generator produces 500 megawatts of power per cubic meter. However, as their name implies, such generators require an explosion—one that destroys the ferromagnet, even as it produces power.
Among the potential applications, Galfenol-powered devices could be used as wireless impact detectors. "Essentially, we could fabricate small devices that send out a detectable electromagnetic wave when a mechanical pulse moves through it," Domann said. These devices could be embedded in vehicles—military or civilian—to detect collisions. Because electromagnetic waves travel three orders of magnitude faster than mechanical waves, information about the impact could be transmitted ahead of the waves created by the impact.
This picture is of the experimental setup showing the Hopkinson bar
First generation silicon solar cells have been the mainstay of photovoltaic (PV) energy conversion for many years now due to their high stability and efficient energy conversion, but their opacity and expense mean that alternatives are now being actively sought for modern building and vehicle applications. Thin film PVs (second generation solar cells) are lightweight and flexible, but are expensive because they are created from rare materials using complex structures requiring high-temperature production processes.
Now, utilizing such materials as thin-film perovskite, the third generation of solar cell is currently being developed for commercial use in the not-too-distant future with the promise of greater power conversion efficiencies, simpler fabrication processes, and lower cost.
In this vein, the PolyU researchers have developed their own version of the third generation solar cell using semitransparent perovskite with graphene used as the electrodes. Being exceptionally thin but with high conductivity and low cost, graphene makes an ideal choice for semitransparent solar cells as it allows light to be absorbed from both sides. As such, the researchers envisage these devices potentially able to be used in windows, louvers, and building roof surfaces, thereby increasing the available surface area for collecting solar energy.
With a claimed power conversion efficiency of around 12 percent, the PolyU solar cells outperform standard transparent and semi-transparent versions hands-down. The potential to be produced at less than HK $0.50 (US $0.06)/Watt also means a greater than 50 percent saving on the cost of conventional silicon solar cells.
While graphene has been around for more than a decade now and is highly-efficient as a conductor in its own right, the PolyU researchers decided to further enhance the conductivity of graphene to meet their specific requirements. To do this, the graphene was coated with a patina of PEDOT:PSS conductive polymer (poly(3,4-ethylenedioxythiophene) polystyrene sulfonate) – the same ingredient recently used by KAIST scientists in the production of weavable LED fibers – that also acted as an adhesion layer to the perovskite during the process of lamination.
To promote power conversion efficiency, the researchers found that by multilayering graphene through chemical vapor deposition to create transparent electrodes, the sheet resistance of the electrodes was additionally reduced while the exceptional transparency of the electrodes was retained. Finally, the performance of the device was further improved by enhancing the degree of contact between the top graphene electrodes and the hole transport layer on the perovskite film.
According to the researchers, the exceptional flexibility of graphene and the simplified preparation of the cells means that the PolyU device could be eminently suitable for mass production via direct printing or using a roll-to-roll process. In this way, semitransparent solar cells may well provide a greater uptake of PV panels across markets not currently serviced by traditional, opaque devices.
The results of this research were published in the journal Advanced Materials.
Source: Hong Kong Polytechnic University
http://nextbigfuture.com/
September 29, 2015
Galfenol can convert 70 percent of an applied mechanical energy into magnetic energy
Galfenol converts energy with high efficiency; it is able to turn roughly 70 percent of an applied mechanical energy into magnetic energy, and vice versa. (A standard car, by contrast, converts only about 15 to 30 percent of the stored energy in gasoline into useful motion.) Significantly, the magnetoelastic effect can be used to generate electricity. "If we wrap some wires around the material, we can generate an electrical current in the wire due to a change in magnetization," Domann said.
Galfenol in experiments using a device called a Split-Hopkinson Pressure Bar to generate high amounts of compressive stress (e.g., powerful impacts). They found that when subjected to impacts, Galfenol generates as much as 80 megawatts of instantaneous power per cubic meter.
By way of comparison, a device known as an explosively driven ferromagnetic pulse generator produces 500 megawatts of power per cubic meter. However, as their name implies, such generators require an explosion—one that destroys the ferromagnet, even as it produces power.
Among the potential applications, Galfenol-powered devices could be used as wireless impact detectors. "Essentially, we could fabricate small devices that send out a detectable electromagnetic wave when a mechanical pulse moves through it," Domann said. These devices could be embedded in vehicles—military or civilian—to detect collisions. Because electromagnetic waves travel three orders of magnitude faster than mechanical waves, information about the impact could be transmitted ahead of the waves created by the impact.
This picture is of the experimental setup showing the Hopkinson bar
surrounded by a water-cooled electromagnet. A cylinder of Galfenol
is
inside of the electromagnet, sandwiched between the Hopkinson bars.
The
magnet was used to apply a wide range of static magnetic fields to
Galfenol while it was mechanically impacted. Credit: John Domann/UCLA
Journal of Applied Physics - High strain-rate magnetoelasticity in Galfen
This paper presents the experimental measurements of a highly magnetoelastic material (Galfenol) under impact loading. A Split-Hopkinson Pressure Bar was used to generate compressive stress up to 275 MPa at strain rates of either 20/s or 33/s while measuring the stress-strain response and change in magnetic flux density due to magnetoelastic coupling. The average Young's modulus (44.85 GPa) was invariant to strain rate, with instantaneous stiffness ranging from 25 to 55 GPa. A lumped parameters model simulated the measured pickup coil voltages in response to an applied stress pulse. Fitting the model to the experimental data provided the average piezomagnetic coefficient and relative permeability as functions of field strength. The model suggests magnetoelastic coupling is primarily insensitive to strain rates as high as 33/s. Additionally, the lumped parameters model was used to investigate magnetoelastic transducers as potential pulsed power sources. Results show that Galfenol can generate large quantities of instantaneous power (80 MW/m3 ), comparable to explosively driven ferromagnetic pulse generators (500 MW/m3 ). However, this process is much more efficient and can be cyclically carried out in the linear elastic range of the material, in stark contrast with explosively driven pulsed power generators.
A Kolsky bar was used to generate large constant strain rates in Galfenol, and measure the stress-strain response, as well as the change in magnetic flux density due to magnetoelastic coupling. The experimental results indicate that the average Young's modulus of Galfenol is invariant with increasing strain rates of up to 33/s. The measured voltage was proportional to strain rate, with a more rounded appearance, attributed to dynamic magnetic effects. Furthermore, the measured voltage and change in flux were highly dependent on bias field strength. A lumped parameters model was created that effectively simulates the measured pickup coil voltages in response to an applied stress pulse. The model suggests that magnetoelastic coupling is relatively insensitive to strain rates as high as 33/s. The model also suggests that Galfenol can generate large quantities of instantaneous power, comparable to those created by explosively driven ferromagnetic pulse generators. However, this process is much more efficient and can be cyclically carried out in the linear elastic range of the material, in stark contrast with explosively driven pulsed power generators.
SOURCES- UCLA, Phys.org, Journal of Applied Physics
Journal of Applied Physics - High strain-rate magnetoelasticity in Galfen
This paper presents the experimental measurements of a highly magnetoelastic material (Galfenol) under impact loading. A Split-Hopkinson Pressure Bar was used to generate compressive stress up to 275 MPa at strain rates of either 20/s or 33/s while measuring the stress-strain response and change in magnetic flux density due to magnetoelastic coupling. The average Young's modulus (44.85 GPa) was invariant to strain rate, with instantaneous stiffness ranging from 25 to 55 GPa. A lumped parameters model simulated the measured pickup coil voltages in response to an applied stress pulse. Fitting the model to the experimental data provided the average piezomagnetic coefficient and relative permeability as functions of field strength. The model suggests magnetoelastic coupling is primarily insensitive to strain rates as high as 33/s. Additionally, the lumped parameters model was used to investigate magnetoelastic transducers as potential pulsed power sources. Results show that Galfenol can generate large quantities of instantaneous power (80 MW/m3 ), comparable to explosively driven ferromagnetic pulse generators (500 MW/m3 ). However, this process is much more efficient and can be cyclically carried out in the linear elastic range of the material, in stark contrast with explosively driven pulsed power generators.
A Kolsky bar was used to generate large constant strain rates in Galfenol, and measure the stress-strain response, as well as the change in magnetic flux density due to magnetoelastic coupling. The experimental results indicate that the average Young's modulus of Galfenol is invariant with increasing strain rates of up to 33/s. The measured voltage was proportional to strain rate, with a more rounded appearance, attributed to dynamic magnetic effects. Furthermore, the measured voltage and change in flux were highly dependent on bias field strength. A lumped parameters model was created that effectively simulates the measured pickup coil voltages in response to an applied stress pulse. The model suggests that magnetoelastic coupling is relatively insensitive to strain rates as high as 33/s. The model also suggests that Galfenol can generate large quantities of instantaneous power, comparable to those created by explosively driven ferromagnetic pulse generators. However, this process is much more efficient and can be cyclically carried out in the linear elastic range of the material, in stark contrast with explosively driven pulsed power generators.
SOURCES- UCLA, Phys.org, Journal of Applied Physics
http://nextbigfuture.com/
September 29, 2015
Solar Cells Will be Made Obsolete by 3D rectennas aiming at 40-to-90% efficiency
A new kind of nanoscale rectenna (half antenna and half rectifier) can convert solar and infrared into electricity, plus be tuned to nearly any other frequency as a detector.
Right now efficiency is only one percent, but professor Baratunde Cola and colleagues at the Georgia Institute of Technology (Georgia Tech, Atlanta) convincingly argue that they can achieve 40 percent broad spectrum efficiency (double that of silicon and more even than multi-junction gallium arsenide) at a one-tenth of the cost of conventional solar cells (and with an upper limit of 90 percent efficiency for single wavelength conversion).
It is well suited for mass production, according to Cola. It works by growing fields of carbon nanotubes vertically, the length of which roughly matches the wavelength of the energy source (one micron for solar), capping the carbon nanotubes with an insulating dielectric (aluminum oxide on the tethered end of the nanotube bundles), then growing a low-work function metal (calcium/aluminum) on the dielectric and voila--a rectenna with a two electron-volt potential that collects sunlight and converts it to direct current (DC).
"Our process uses three simple steps: grow a large array of nanotube bundles vertically; coat one end with dielectric; then deposit another layer of metal," Cola told EE Times. "In effect we are using one end of the nanotube as a part of a super-fast metal-insulator-metal tunnel diode, making mass production potentially very inexpensive up to 10-times cheaper than crystalline silicon cells."
For commercialization, billions or even trillions of carbon-nanotube bundles could be grown side-by-side, ramping up the power output into the megaWatt range, after optimization for higher efficiency.
"We still have a lot of work to do to lower contact resistance which will improve the impedance match between the antenna and diode, thus raising efficiency," Cola told us."Our proof-of-concept was tuned to the near-infrared. We used infrared-, solar- and green laser-light and got efficiencies of less than one percent, but what was key to our demo was we showed our computer model matched our experimental results, giving us the confidence that we can improve the efficiency up to 40 percent in just a few years."
For the future, Cola's group has a three tiered goal--first develop sensor applications that don't require high efficiencies, second to get the efficiency to 20 percent for harvesting waste heat in the infrared spectrum, then start replacing standard solar cells with 40 percent efficient panels in the visible spectrum. The team is also seeking suitable flexible substrates for applications that require bending.
capped with a metal-oxide-metal tunneling diode. (Credit: Thomas
Bougher)
(Source: Georgia Tech)
Nature Nanotechnology - A carbon nanotube optical rectenna
An optical rectenna—a device that directly converts free-propagating electromagnetic waves at optical frequencies to direct current—was first proposed over 40 years ago, yet this concept has not been demonstrated experimentally due to fabrication challenges at the nanoscale. Realizing an optical rectenna requires that an antenna be coupled to a diode that operates on the order of 1 pHz (switching speed on the order of 1 fs). Diodes operating at these frequencies are feasible if their capacitance is on the order of a few attofarads but they remain extremely difficult to fabricate and to reliably couple to a nanoscale antenna. Here we demonstrate an optical rectenna by engineering metal–insulator–metal tunnel diodes, with a junction capacitance of ∼2 aF, at the tip of vertically aligned multiwalled carbon nanotubes (∼10 nm in diameter), which act as the antenna. Upon irradiation with visible and infrared light, we measure a d.c. open-circuit voltage and a short-circuit current that appear to be due to a rectification process (we account for a very small but quantifiable contribution from thermal effects). In contrast to recent reports of photodetection based on hot electron decay in a plasmonic nanoscale antenna a coherent optical antenna field appears to be rectified directly in our devices, consistent with rectenna theory. Finally, power rectification is observed under simulated solar illumination, and there is no detectable change in diode performance after numerous current–voltage scans between 5 and 77 °C, indicating a potential for robust operation.
(Source: Georgia Tech)
Nature Nanotechnology - A carbon nanotube optical rectenna
An optical rectenna—a device that directly converts free-propagating electromagnetic waves at optical frequencies to direct current—was first proposed over 40 years ago, yet this concept has not been demonstrated experimentally due to fabrication challenges at the nanoscale. Realizing an optical rectenna requires that an antenna be coupled to a diode that operates on the order of 1 pHz (switching speed on the order of 1 fs). Diodes operating at these frequencies are feasible if their capacitance is on the order of a few attofarads but they remain extremely difficult to fabricate and to reliably couple to a nanoscale antenna. Here we demonstrate an optical rectenna by engineering metal–insulator–metal tunnel diodes, with a junction capacitance of ∼2 aF, at the tip of vertically aligned multiwalled carbon nanotubes (∼10 nm in diameter), which act as the antenna. Upon irradiation with visible and infrared light, we measure a d.c. open-circuit voltage and a short-circuit current that appear to be due to a rectification process (we account for a very small but quantifiable contribution from thermal effects). In contrast to recent reports of photodetection based on hot electron decay in a plasmonic nanoscale antenna a coherent optical antenna field appears to be rectified directly in our devices, consistent with rectenna theory. Finally, power rectification is observed under simulated solar illumination, and there is no detectable change in diode performance after numerous current–voltage scans between 5 and 77 °C, indicating a potential for robust operation.
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