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Showing posts with label Thorium. Show all posts
Showing posts with label Thorium. Show all posts
Sunday, May 10, 2015
Thursday, May 29, 2014
Thorium backed as a 'future fuel'
31 October 2013
Last updated at 05:41 ET
By Roger Harrabin Environment analyst, Halden in Norway
It is also more difficult to use thorium for the production of nuclear weapons.
His comments will add to growing levels of interest in thorium, but critics warn that developing new reactors could waste public funds.
Mr Blix, the former Swedish foreign minister, told BBC News: "I’m a lawyer not a scientist but in my opinion we should be trying our best to develop the use of thorium. I realise there are many obstacles to be overcome but the benefits would be great.
"I am told that thorium will be safer in reactors - and it is almost impossible to make a bomb out of thorium. These are very major factors as the world looks for future energy supplies."
His enthusiasm is shared by some in the British nuclear
establishment. Scientists at the UK’s National Nuclear Laboratory (NNL)
have been encouraged by the government to help research on an Indian
thorium-based reactor, and on a test programme in Norway.
The Norway tests at the OECD’s nuclear trials facility in Halden are conducted in a Bond-style underground bunker.
A couple of charming Nordic homes perch on top of a hill at the edge of the town. Below them a garage door in a cliff face leads into a tunnel deep into the hill where the reactor hall lies.
In theory, at least, the mountain protects the town from an accident.
The thorium tests are being carried out by a private firm, Thor Energy (the element itself was discovered in Norway in 1828 and named after the Norse god of thunder).
The company hopes to get thorium licensed alongside uranium in current water-cooled reactor plants.
The British government says it would be useful to increase the fuel options for nuclear operators, as thorium is believed to be three times more plentiful than uranium. It is also currently being produced as a by-product from mining rare earths.
Staff from NNL have been advising Thor on the use of mixed oxide fuels (MOX). NNL has also been helping the Indian authorities develop a thorium reactor, as India sits on top of the world’s biggest thorium reserves.
The Thor project represents an evolutionary approach, using thorium in existing reactors together with uranium or plutonium.
Oystein Asphjell, chief executive of Thor Energy told BBC News: "There is lots of thorium in the world, very well distributed all over the globe. In operations, in a reactor, it has some chemical and physical properties that make it really superior to uranium as well. On the waste side, we don’t generate long lived waste."
China is going for a revolutionary approach, devising a next-generation reactor which its supporters say will enable thorium to be used much more safely than uranium.
When a uranium reactor overheats and the fuel rods can’t contain the chain reaction, as happened at Fukushima, the crisis continues. If something happened to a thorium reactor, technicians could simply switch off the stimulus which comes from uranium or plutonium in a small feeder plant and the thorium reaction would halt itself.
Prof Carlo Rubbia from Cern previously told BBC News: "Thorium will be able to shut itself off without any human intervention... You just switch off the beam.”
"There are also no long-lived waste products... We estimate that after something like 400-500 years all the radioactivity will be dissipated away."
These advantages, if they were realised, would be huge. But thorium still has many technical problems to overcome. What is more, countless billions have been ploughed into uranium-based research and development, and in the words of Mr Blix, uranium has a very deep furrow, backed by vested interests.
Canada, China, Germany, India, the Netherlands, the UK and the US have experimented with thorium as a substitute fuel in the past.
Questions are being raised, though, about the advisability of
pinning the world’s energy ambitions on another nuclear dream.
Environmentalists often allege that if renewable power had commanded a
fraction as much research funding as nuclear it would already be much
cheaper and more common.
Dr Nils Bohmer, a nuclear physicist working for a Norwegian environmental NGO, Bellona, said developing thorium was a costly distraction from the need to cut emissions immediately to stave off the prospect of dangerous climate change.
"The advantages of thorium are purely theoretical," he told BBC News.
"The technology development is decades in the future. Instead I think we should focus on developing renewable technology - for example offshore wind technology - which I think has a huge potential to develop.”
If thorium ever makes it as a commercial nuclear fuel, uranium may be seen as a massive and costly diversion. Some supporters of thorium believe that it was bypassed in the past because governments wanted the plutonium from certain conventional reactors to make atomic bombs.
They believe thorium was rejected because it was simply too safe.
http://www.bbc.co.uk/news/
By Roger Harrabin Environment analyst, Halden in Norway
Thorium could prove to be safer in reactors than uranium
Nuclear scientists are being urged by the former UN weapons inspector Hans Blix to develop thorium as a new fuel.
Mr Blix says that the radioactive element may prove much safer in reactors than uranium.It is also more difficult to use thorium for the production of nuclear weapons.
His comments will add to growing levels of interest in thorium, but critics warn that developing new reactors could waste public funds.
Mr Blix, the former Swedish foreign minister, told BBC News: "I’m a lawyer not a scientist but in my opinion we should be trying our best to develop the use of thorium. I realise there are many obstacles to be overcome but the benefits would be great.
"I am told that thorium will be safer in reactors - and it is almost impossible to make a bomb out of thorium. These are very major factors as the world looks for future energy supplies."
Hans Blix says the world should try its best to develop thorium
The Norway tests at the OECD’s nuclear trials facility in Halden are conducted in a Bond-style underground bunker.
A couple of charming Nordic homes perch on top of a hill at the edge of the town. Below them a garage door in a cliff face leads into a tunnel deep into the hill where the reactor hall lies.
In theory, at least, the mountain protects the town from an accident.
The thorium tests are being carried out by a private firm, Thor Energy (the element itself was discovered in Norway in 1828 and named after the Norse god of thunder).
The British government says it would be useful to increase the fuel options for nuclear operators, as thorium is believed to be three times more plentiful than uranium. It is also currently being produced as a by-product from mining rare earths.
Staff from NNL have been advising Thor on the use of mixed oxide fuels (MOX). NNL has also been helping the Indian authorities develop a thorium reactor, as India sits on top of the world’s biggest thorium reserves.
Inside Norway's experimental nuclear power plant
Oystein Asphjell, chief executive of Thor Energy told BBC News: "There is lots of thorium in the world, very well distributed all over the globe. In operations, in a reactor, it has some chemical and physical properties that make it really superior to uranium as well. On the waste side, we don’t generate long lived waste."
China is going for a revolutionary approach, devising a next-generation reactor which its supporters say will enable thorium to be used much more safely than uranium.
When a uranium reactor overheats and the fuel rods can’t contain the chain reaction, as happened at Fukushima, the crisis continues. If something happened to a thorium reactor, technicians could simply switch off the stimulus which comes from uranium or plutonium in a small feeder plant and the thorium reaction would halt itself.
Prof Carlo Rubbia from Cern previously told BBC News: "Thorium will be able to shut itself off without any human intervention... You just switch off the beam.”
"There are also no long-lived waste products... We estimate that after something like 400-500 years all the radioactivity will be dissipated away."
These advantages, if they were realised, would be huge. But thorium still has many technical problems to overcome. What is more, countless billions have been ploughed into uranium-based research and development, and in the words of Mr Blix, uranium has a very deep furrow, backed by vested interests.
Canada, China, Germany, India, the Netherlands, the UK and the US have experimented with thorium as a substitute fuel in the past.
The nuclear trials at Halden are conducted underground
Dr Nils Bohmer, a nuclear physicist working for a Norwegian environmental NGO, Bellona, said developing thorium was a costly distraction from the need to cut emissions immediately to stave off the prospect of dangerous climate change.
"The advantages of thorium are purely theoretical," he told BBC News.
"The technology development is decades in the future. Instead I think we should focus on developing renewable technology - for example offshore wind technology - which I think has a huge potential to develop.”
If thorium ever makes it as a commercial nuclear fuel, uranium may be seen as a massive and costly diversion. Some supporters of thorium believe that it was bypassed in the past because governments wanted the plutonium from certain conventional reactors to make atomic bombs.
They believe thorium was rejected because it was simply too safe.
The Advantages of Thorium Reactors (long)
http://slowfacts.wordpress.com/
November 2, 2011
ARE ALL POWER PLANTS THE SAME? In a word, no, but a full answer requires more than a word. The one page answer is here. We’ll need a full answer to avoid simplistic praise or trite condemnation of complex energy solutions. A friend asked me to explain the advantages of Thorium reactors so I’ll compare Thorium with other ways to generate electrical power. The short list of comparisons are-
Safety, Environmental advantages, Ease of installation and site flexibility, Low financial costs, and Necessity.
WHAT IS THE THORIUM FUELED REACTOR? Let’s dive into a definition first so the nuclear geeks won’t nag me and we’ll all know what we’re talking about. In this case we’re considering the advantages of a molten salt, Thorium fueled, graphite moderated, unity breeder reactor of about 100 million watts electrical output. The reactor design has separate fluids for the core and breeding blanket. Both fluids are a mixture of lithium fluoride (LiF) and beryllium fluoride (BeF2), abbreviated as FLiBe (Filbe). The fertile material in the breeding blanket salt is natural Thorium (Th232). The fissile material in the core coolant salt is Uranium 233. The power extraction cycle is a reheated Brayton (gas) cycle. Did you get all that and memorize it? I’ll explain more as we go along. For now we will simply call this reactor a Liquid Fluoride Thorium Reactor, or LFTR.
HOW ARE THORIUM REACTORS DIFFERENT? I want to highlight this reactor’s unusual features because this is not the way your grandparents kept the lights on. The LFTR uses a liquid as both a coolant and a fuel. Though exotic for a reactor, your car engine does the same thing. In this reactor the coolant and fuel are a molten salt that is solid at room temperature and can be heated until it glows orange hot and still won’t boil. Now that’s a little different.
The reactor core is the important component that makes the fuel reactive, and without the core the fuel cannot sustain a chain reaction. We can put all the fuel in one tank and it will not react. We can spill it on the floor and it will not react, other than blistering the paint as it cools. We can mix the FLiBe salt with water or air and the salt sits there. That is a good thing, and a little different from other reactors you’ve heard about.
We feed this reactor every few days as the plant operates rather than once a year during a plant shutdown. We add fuel as we need it so there is not a year’s worth of excess reactivity we need to control. We also clean the fuel every few days as it becomes contaminated rather than removing years of accumulated fission products at one time. This means that the fuel is continually cleaned of radioactivity. This is important because the fission products generate heat as they decay. We limit the amount of heat the fuel will generate by removing the fission products and storing them outside the core. That is different.
In the LFTR, the part of the plant that makes electricity runs on a hot gas just like a jet engine. Most nuclear plants run on high pressure steam like a steam locomotive. The LFTR operates at high temperature so it can use air as a coolant rather than needing a large body of water. That is a little different than most reactors, and all these differences seem unusual at first.
A Liquid Fluoride Thorium Reactor can fit on a few volleyball courts rather than needing to be as large as a football stadium. Sure, you could make a large LFTR, but you don’t have to. True, the small power plant doesn’t put out as much power as a huge nuclear plant but it is much easier to locate and build a small plant. The issue of a small plant versus a large plant is the same issue of a small car versus a bus. You can fit the small plant were you need it. One huge advantage of a small power plant is that you can deliver the pieces by truck and have the plant build it in a few months rather than taking many years. The small LFTR is closer in size to a portable generating station than the huge building we usually think of as a power plant. Those are a few of the differences, but let’s also look at what the LFTR has in common with conventional plants.
WHAT ARE THE ADVANTAGES OF A LIQUID FLUORIDE THORIUM REACTOR?
SAFETY- Safety comes first. I’m interested in Thorium because it can help people live better lives so we can’t compromise safety. For LFTR to be a benefit, the entire system from fabrication to ultimate disposal must be low risk. In fact, the low risk is a major reason I’m attracted to these power plants. The LFTR can have an intrinsically safe design. Intrinsic safety means the plant will safely shut down if-
- we physically break the reactor into pieces,
- the load goes away and the plant stops providing electrical power to the grid,
- we lose internal power in the plant.
How could we break a reactor into pieces and have it remain “safe”? To do so, the reactor has to operate in its most reactive configuration. That means we won’t get a local power spike if things shift around inside the reactor, even if they shift a lot. Sure, the power plant has active electronic controls, but it also has a passive control system. By design, the power from the core drops as the reactor heats up. In fact, if you stop cooling the reactor the power will fall dramatically. This provides intrinsic thermal stability. If we allow the molten salt to get too hot then the salt will automatically drain into a shutdown tank. An operator does not have to operate this safety system: it only needs gravity to operate, and gravity is pretty reliable. This provides walk away safety. A temperature stable reactor is both safe AND flexible. The reactor responds to the electrical load and provides more power as the load increases. Natural stability makes the reactor easier to operate. For example, you don’t want the reactor to suddenly shut down if the fuel concentration is slightly low, nor do you want a significant power surge if you slightly increase the fuel concentration. Inherent temperature stability provides both safety and an operating cushion.
Clean Fuel- We create another safety feature by removing fission products from the fuel as the fission products accumulate. These materials decay rapidly and generate heat. They must be cooled and isolated for a few hundred years before they are safe to be around. They don’t belong in a power plant, and they can be removed from the LFTR fuel stream. This means they are not part of an accident scenario if we “break” the reactor.
We need to compare LFTR with conventional nuclear power plants because of the significant difference in the amount and type of nuclear waste they produce. A conventional nuclear plant starts with fuel concentrated to 3% U235. That means that 97% of the fuel doesn’t contribute to making electricity but it can form long term high level nuclear waste. The LFTR could not be more different. More than 99% of the Thorium found in nature is suitable as nuclear fuel to make electricity. Thorium is added to the reactor as salt, while conventional reactors add uranium as ceramic pellets wrapped in a stainless steel tube called cladding. The cladding and non-consumed nuclear fuel are the largest source of high level radioactive waste in conventional powerplants. Thorium has none of these materials. The volume of high level waste from thorium is less than 2% of the waste from conventional spent nuclear fuel. The nuclear waste from thorium is short lived compared to conventional nuclear waste. I contend that the waste is suitable for open burial once the waste is less reactive than the original ore. That requires a storage period of about 300 years.
No Bombs Here- Atomic weapons do not directly involve reactor operation, but let’s discuss them anyway. The simple facts are you can make a weapon out of almost anything given enough time and money. The Liquid Fluoride Thorium Reactor is no exception. Given enough time and money it is possible to harvest materials from the reactor to build some kind of weapon. Please understand that simply because something is possible does not mean it is likely. There are several ways to make an atomic bomb. Using a LFTR would be one of the hardest methods. The other ways are not easy, but they are significantly easier than trying to create weapons grade plutonium or uranium from this fluid fueled reactor.
Low Pressure and Inert- The LFTR is a low pressure reactor, and that significantly adds to safety. It operates at a few atmospheres pressure, or about the pressure inside a soccer ball or your car tire. This low internal pressure eliminates the need for the thick walled reactor pressure vessel that is used on water cooled reactors. The low pressure and inert materials eliminate the potential for a steam explosion that is inherent in the design of a pressurized water reactor. They eliminate the potential of a sodium fire that is inherent in a sodium cooled fast reactor, or the lithium fire that is inherent in many fusion reactor designs. There are simply fewer ways to create an explosive accident with a salt cooled reactor.
Easy to Package- The light, compact, and passively stable power plant is easily hardened to withstand earthquakes. The plant does not have to be located at the edge of a lake or ocean, so it is much less likely to be damaged by a Tsunami. Air cooling is unusually reliable. Some locations have run out of water, but I’ve never heard of a site which ran out of air. (Yes, a sandstorm or volcanic ash eruption would be an exception. Those events usually offer considerable warning.) There are other advantages.
WHAT ARE THE ENVIRONMENTAL ADVANTAGES OF A THORIUM REACTOR?
Low Carbon Footprint- Despite its considerable size, a conventional nuclear power plant has a very low carbon footprint that lies between the footprint of hydro power and wind. All three have a smaller footprint than solar power. The LFTR is better than conventional nuclear, and the differences in carbon footprint are sizable. The average person living the western lifestyle consumes the energy contained in a cube of coal that is 5 meters on a side. For comparison, the same energy is contained in a golf ball sized sphere of Thorium. Most of the carbon footprint from conventional nuclear power comes from mining, refining and concentrating uranium fuel. Thorium is much more plentiful than uranium and is a waste byproduct of rare-earth mining. The LFTR runs on natural Thorium without isotopic concentration. The massive concrete structure of a conventional power plant also adds to its carbon footprint. The LFTR power plant does not require a concrete building designed to contain a violent steam explosion. All of these differences significantly reduce the carbon footprint of LFTR.
Small Power Plants are Easier to Build- Small size simply makes it easier to locate a LFTR where power is needed. The LFTR and conventional nuclear plants produce similar energy per area, and both are quite different from alternative energy sources. A 100 mega watt LFTR takes an area the size of 3 tennis courts, or about half an acre. A wind farm takes 50 times more area, and that excludes the backup power plant it requires. A solar power plant takes 48 thousand times more area, and that excludes the backup power plant it requires. Note that the area required to provide power to three quarter of a million people changed from the size of a house lot to the area of a mid-sized city. It is simply easier to license a small site than to license a much much larger one. Rail access is not required, but road access is necessary for delivery and periodic maintenance.
High Efficiency Reduces Waste Heat- High thermal efficiency means that less heat is released into the environment for each watt of electricity we produce. Compared to electrical energy from LFTR, a coal fired power plant releases 12 percent more heat to the environment. A conventional nuclear power plant releases 66 percent more heat to the environment. A solar photovoltaic generator releases 81 times more heat to the environment. I thought we were trying to keep the planet cool.
Ease of Installation and Site Flexibility- Delivering the parts of a nuclear plant by truck is a small benefit. The small plant does not require water-front access for delivery of materials or for plant cooling. Air cooling allows the plant to be located on the side of a mountain or in the desert, though some water is required for the human operators. The revolutionary aspect of a small reactor is the fact that the power plant come from a factory in standard pre-assembled modules. The conventional reactor is built on site the way a stick-built house is built one part at a time. In contrast, the LFTR is assembled on site like a mobile home. This means that site preparation and fabrication occur in parallel. Like mobile homes, the reactors are built on a continuous basis and the next customer simply selects a delivery date.
The LFTR may be small, but it is not weak. The semi-buried design minimizes the exposure of the plant to accidental storms and deliberate attack.
DOES THIS POWER PLANT MAKE FINANCIAL SENSE?
Cost is the result of the previous factors, and each has a cumulative effect.
- Rapid installation decreases financial uncertainty. The installation site can be prepared quickly because the power plant is small and simple. Large cooling towers, cooling canals, rail lines, waste handling pools or heavy containment buildings are not required. The size and location of the electrical demand does not need to be forecast eight years in advance. This reduces the risk that the plant would be built and then sit idle if the local economy has a downturn.
- Quick delivery means that construction interest costs are low. The plant quickly begins to generate revenue rather than having capital costs tied up for many years during fabrication, construction and certification of a custom plant.
- License approval is easier because the power plants are standardized. There are many identical units with a long learning curve.
- The modular plant can be removed and reinstalled at another site if the political climate forces the plant to close. No one wants a project to fail, but it is reassuring that substantial costs can be recovered if the project is cancelled.
- Spent fuel presents a long term financial risk. LFTR presents significantly decreased fuel storage and handling costs compared with conventional nuclear plants. The low cost is due to high fuel efficiency and the vastly reduced amount of high level radioactive waste.
- The air cooled Brayton cycle allows the plant to rapidly follow a changing electrical load. Plants that can follow demand receive higher prices for each watt they generate compared to plants that can only provide base-load power.
- The plants must be built and must also be removed at the end of their lifetime. There are several decommissioning options. The power core could be replaced and the switch yard reused. To do so, the unit would be defueled and the empty reactor and moderator assembly would be removed for burial. If regulations allow, the unit would be defueled and the empty reactor and moderator assembly entombed in place. This keeps decommissioning cost low.
- Thorium provides an inexpensive nuclear fuel. (Thorium is about as abundant as Tin.) Thorium is considered a waste material in rare earth mining and known supplies are sufficient to provide the world’s current population with electrical power for several thousand years. We have more fuel than we need for current demand and we haven’t looked very hard to find more. This means the long term price of Thorium should be stable
- The reactor can be designed to start with minimal outside power. In contrast, some power plants require up to 15% of their rated power in order to start operation. A cluster of LFTRs might have one reactor equipped for a “black start”, and “black start” power plants earn higher fees. Black start power often comes from hydro plants and combustion turbines. LFTRs add to that option which conventional nuclear plants cannot.
WHAT IS THE BEST FEATURE OF THIS REACTOR? I’ve described the improvements that Thorium reactors offer over other power sources. The best feature is not one of them, but all of them in combination. The best feature is that molten salt reactors offer many improvements without major technical weaknesses.
WHY DON’T WE HAVE THESE REACTORS MAKING POWER NOW? That answer belongs in another post.
S.F. Doug, this one is for you.
China enters race to develop nuclear energy from thorium
http://www.theguardian.com/environment/blog
Scientists and private firms in China have embarked on a major new push to develop liquid-fluoride thorium reactor technology
• Video: Manchester Report - Thorium nuclear power
• Video: Manchester Report - Thorium nuclear power
Thorium pellets. Photograph: Pallava Bagla/Corbis
Imagine how the nuclear energy
debate might differ if the fuel was abundant and distributed across the
world; if there was no real possibility of creating weapons-grade
material as part of the process; if the waste remained toxic for
hundreds rather than thousands of years; and if the power stations were
small and presented no risk of massive explosions.
What you're imagining could fairly soon be reality judging from a little-noticed development in China last month.
Two years ago, as part of the Manchester Report, a panel of experts assembled by the Guardian selected nuclear power based on thorium rather the uranium as one of the 10 most promising solutions to climate change.
Thorium – which is found in large quantities across much of the world – could be used to create nuclear energy in various ways. But the approach that impressed the Manchester Report panel so much was a currently obscure technology called the liquid-fluoride thorium reactor (LFTR).
I wrote at the time:
Despite not making a ripple in the wider press, there's a chance this development could be very significant. If the advocates of LFTRs are proved correct – and their arguments are certainly very compelling – then the Chinese could be taking one of the first substantial steps in a new type of nuclear race. And the stakes are high: as Sorensen reports, the project "aims not only to develop the technology but to secure intellectual property rights to its implementation". It will be very interesting to see what happens next.
What you're imagining could fairly soon be reality judging from a little-noticed development in China last month.
Two years ago, as part of the Manchester Report, a panel of experts assembled by the Guardian selected nuclear power based on thorium rather the uranium as one of the 10 most promising solutions to climate change.
Thorium – which is found in large quantities across much of the world – could be used to create nuclear energy in various ways. But the approach that impressed the Manchester Report panel so much was a currently obscure technology called the liquid-fluoride thorium reactor (LFTR).
I wrote at the time:
"This technology was developed by the US military in the 1950s and 1960s and was shown to have many benefits. For example, reactors of this type can be smaller than conventional uranium reactors, partly thanks to their low-pressure operation. Despite its early promise, research into liquid-fluoride thorium reactors was abandoned – the most likely reason being that the technology offered no potential for producing nuclear weapons."There's a big difference between a demonstrably good idea and a multimillion-dollar research and development programme, however, so it's exciting to hear about a major new push to actually develop LFTR technology in China. Thorium-energy expert Kirk Sorensen recently blogged about the announcement of the new scheme at the Chinese National Academy of Sciences in late January. Technology journalist Andrew Orlowski followed up with a story claiming that a private company in China is aiming to build a prototype within five years that can produce electricity at for as little as 6.8p per kilowatt hour (much cheaper than the retail price of power in the UK today).
Despite not making a ripple in the wider press, there's a chance this development could be very significant. If the advocates of LFTRs are proved correct – and their arguments are certainly very compelling – then the Chinese could be taking one of the first substantial steps in a new type of nuclear race. And the stakes are high: as Sorensen reports, the project "aims not only to develop the technology but to secure intellectual property rights to its implementation". It will be very interesting to see what happens next.
The nuke that might have been
Difference Engine
http://www.economist.com/blogs/babbage
DOES the world need more nuclear power or less? Seared by the disaster at the Fukushima Dai-ichi nuclear plant in March 2011, Japan has now taken all its commercial reactors offline. The last was powered down on September 16th. Tokyo Electric Power, owner of the ill-fated reactors on the Fukushima coast, still hopes to restart an idled nuclear plant in Niigata prefecture next July—if it can overcome entrenched local opposition.
Meanwhile, measures are underway in Germany and Switzerland to phase out their nuclear stations. Another 11 European countries, plus Australia and New Zealand, remain adamantly opposed to nuclear power. In recent years, more reactors around the world have closed than opened.
Yet nuclear reactors do one thing no other mainstream source of electricity can boast: they generate large blocks of power without producing carbon dioxide in the process. Hydro-electricity is largely carbon-free, but most suitable sites have long since been exploited. Certainly, renewables like solar, wind and biomass can deliver power largely free of greenhouse gases. But renewables are nowhere near reliable nor cheap enough to displace conventional fuels—be they coal, natural gas, oil or nuclear. Nor can they be scaled up fast enough to meet the world’s insatiable demand for electricity.
Overall, opposition to nuclear power—despite the graphic footage of the nuclear disaster in Fukushima—seems to be on the wane. Last year, The Economist held an online debate on whether the world would be better off without nuclear power. Readers voted 61% to 39% in favour of keeping it (see “Debate on nuclear power”, April 15th 2012).
All told, 40-odd countries—mainly in the Middle East and Asia—have now committed themselves to building their first atomic-power plants, or to adding new ones to their existing nuclear capacity. As the poster-child for pollution, China is keenly aware that it cannot go on building dirty coal-fired power stations indefinitely and needs a cleaner alternative. Hence the 32 new reactors China has under construction, which will add 70 gigawatts of nuclear capacity by 2020. Russia is building ten new ones and India seven. Britain is about to start work on its first nuclear reactor since 1995. With eight of its nine nuclear plants now reaching the end of their lives, Britain plans to build a dozen new ones by 2030.
Today, the nuclear industry’s prospects look brighter than at any time since 1979. That was when a partial meltdown at the Three Mile Island plant in Pennsylvania sent shockwaves around the world—and further orders for nuclear generating capacity began to dry up. The latest reactor designs are far safer. The AP1000, an “advanced passive” reactor from Toshiba’s Westinghouse division, has a huge reservoir of water above the reactor, which is dumped by gravity into the core in an emergency. Westinghouse claims the AP1000 is 100 times safer than present reactors. The broadly similar European Pressurised Reactor, designed by Areva, a French firm, has four redundant safety systems instead of the more usual two or three.
But to Babbage’s mind, the question is not whether their “passive” designs—ie, emergency cooling systems that work by gravity and natural convection instead of electrical valves, relays and pumps—can make them safer. Of that there is no doubt. The question, rather, is why such an inherently flawed design as the light-water reactor (LWR) is still, after all these years, the preferred technology?
Most of today’s reactors, whether they use boiling water or pressurised water, trace their ancestry back to the USS Nautilus, the world’s first nuclear submarine, launched in 1954. At the time, the LWR was just one of many reactor designs that existed either on paper or in the laboratory—using different fuels (uranium-233, uranium-235 or plutonium-239), different coolants (water, heavy water, carbon dioxide or liquid sodium) and different moderators (water, heavy water, beryllium or graphite).
The light-water reactor of the day, with its solid uranium-dioxide fuel and water for both moderator and coolant, was by no means the best. But Admiral Hyman Rickover, the father of America’s nuclear navy, chose it because it could be implemented faster than any of the others, making it possible for Nautilus to be launched on time. The LWR also appealed to Rickover because it produced a lot of bomb-making plutonium as a by-product.
After that, the die was cast. America’s first commercial reactor, the 60-megawatt Shippingport station in Pennsylvania, which started in 1957 (one year after the Calder Hall power station in Britain), used essentially the same light-water design as Nautilus. Henceforth, the rest of America’s commercial reactors would follow suit. Other countries subsequently copied or licensed much the same light-water technology.
In hindsight, that was a terrible mistake. Producing copious quantities of plutonium is just about the last thing a commercial reactor needs to do. It creates huge handling and storage problems as well as all manner of security and proliferation headaches. On top of that, the LWR’s other drawbacks ensured that commercial reactors would henceforth be more expensive to build and costlier to operate than might otherwise have been the case.
For instance, the cooling water in an LWR is not only radioactive and corrosive, but also under extremely high pressure. As a consequence, light-water reactors need to be housed in fortress-like containment buildings in case the cooling system fails and radioactive steam is released into the atmosphere.
Another problem concerns the bundles of rods that contain the uranium-dioxide fuel. These have to be removed from the core after only a few years of burning and stored in cooling ponds, even though no more than 3-5% of the energy in their uranium has been consumed. Their zirconium cladding swells and distorts as a result of temperature differences and radiation damage. There is always the danger of fuel rods rupturing if left in the reactor too long.
Within the fuel rods themselves, the fissile material becomes steadily poisoned by short-lived byproducts, such as xenon-135. This causes dangerous instabilities that make managing the reactor tricky. Such instabilities are what caused the Chernobyl reactor to explode. As if all that were not enough, dealing with a light-water reactor’s long-lived radioactive byproducts remains a Faustian nightmare.
Passive safety features aside, the new generation of reactors being hawked around the world are still basically old-fashioned light-water reactors with solid-fuel cores that are cooled and moderated by water. “Maddeningly,” say two leading light-water critics, “historical, technological and regulatory reasons conspire to make it hugely difficult to diverge from our current path of solid-fuel, uranium-based plants.”
In what has become a classic account of America’s missed opportunity to make nuclear power cleaner, safer and potentially an alternative to coal, Robert Hargraves of Dartmouth College and Ralph Moir, formerly of Lawrence Livermore National Laboratory, have made the most compelling case yet (in the July-August 2010 issue of American Scientist) for reactors that use a liquid fuel instead of a solid one. “Knowing what we now know about climate change, peak oil, Three Mile Island, Chernobyl, and the Deepwater Horizon oil well gushing in the Gulf of Mexico in the summer of 2010, what if we could have taken a different path?” asked the authors.
One advantage of liquid fuels is that they are not subjected to the radiation damage or structural stresses that cause the fuel rods in conventional reactors to swell and distort. Also, because they use a liquid fluoride salt for a coolant, there is no high-pressure water to deal with. Operating at atmospheric pressure, no containment vessel is therefore needed. The xenon gas that poisons the fuel rods in a conventional reactor simply bubbles out of a liquid fuel, while other fission products precipitate out and cease absorbing neutrons from the chain-reaction underway.
The spent fuel from a light-water reactor contains radioactive plutonium with a half-life of over 24,000 years. The fuel used in a liquid-fuel reactor is liquid fluoride laced with thorium. The toxicity of what little waste it produces is 10,000 times less than that from a conventional reactor. Overall, the half-life of a liquid-fuel reactor’s byproducts is measured in hundreds rather tens of thousands of years.
The liquid-fluoride thorium reactor, developed at Oak Ridge National Laboratory in Tennessee during the late 1960s, ran successfully for five years before being axed by the Nixon administration. The reason for its cancellation: it produced too little plutonium for making nuclear weapons. Today, that would be seen as a distinct advantage. Without the Cold War, the thorium reactor might well have been the power plant of choice for utilities everywhere.
Today, the thorium reactor is a non-starter, at least in America and other countries that have invested heavily in light-water technology. But things are different in India, a country with no uranium but an abundance of thorium. India plans to produce 30% of its electricity from thorium reactors by 2050. Being plentiful and cheap, thorium is the only fuel that stands a chance of generating electricity as cheaply as burning coal. As such, it is the only fuel capable of weaning the world off the biggest single polluter of all.
LFTR: A Long-Term Energy Solution?
Posted: 01/09/12 10:54 AM ET
According to the World Health Organization, urban outdoor air pollution is estimated to cause 1.3 million deaths worldwide per year, from respiratory infections, heat disease, and lung cancer. Indoor air pollution is estimated to cause approximately 2 million premature deaths mostly in developing countries. Almost half of these deaths are due to pneumonia in children under 5 years of age. The source in both cases is carbon combustion, from fossil fuels or biomass.
The overwhelming majority of climate scientists tell us that the greenhouse gases generated by human carbon combustion are likely to trigger disastrous global climate change in the decades ahead. Even those who deny this surely must admit that the world would be a better place if we could find an economically feasible and safe alternative to the use of carbon combustion as our primary source of energy.
And so, it came as a surprise to me to learn recently that such an alternative has been available to us since World War II, but not pursued because it lacked weapons applications. When the war ended and nuclear reactors were developed to generate electrical power, the designs adopted were based on the same technologies that were used in the nuclear bombs dropped on Japan. These relied on the fission of uranium-235 (U-235) and plutonium-239 (Pu-239).
U-235 constitutes only 0.72 percent of natural uranium, which is mostly U-238, so costly separation is required. Plutonium is not found in nature and must be "bred" by uranium reactors, also a costly process.
It was well known to physicists of the time that another uranium isotope, U-233, is also fissionable. This isotope also does not occur in nature, but can be bred from the element, thorium, which is very common. However, a reactor breeding U-233 also produces U-232, which has a decay chain that generates high-energy gamma rays. This makes U-233 fusion unusable as a weapon, since these gamma rays are very destructive to a bomb's instrumentation and dangerous to the personnel handling it. Furthermore, U-233 is not an efficient breeder of plutonium, since it contains two fewer neutrons than U-235.
Because of its lack of application to weapons, a promising project at the Oak Ridge National Laboratory that was leading toward a thorium reactor was cancelled by the Nixon administration in 1969 in favor of a more efficient plutonium breeder. The Oak Ridge program was advancing the technology of using molten salt as a reactor fuel rather than the solid rods found in existing naval and commercial reactors. It had successfully operated such a reactor for 22,000 hours before being terminated. Liquid fuel offers great advantages in cost and safety over the solid fuel design.
Currently the liquid fluoride thorium reactor (LFTR) is having a resurgence of interest worldwide. Let me list the advantages of an electrical power plant based on LFTR compared to conventional nuclear and fossil-fuel plants:
• Thorium is plentiful and inexpensive. One ton costing $300,000 can power a 1,000-megawatt plant for a year. One pound of thorium yields as much power as 300 pounds of uranium or 3.5 million tons of coal.
• Unlike conventional high-pressure water reactors, LTFR operates at atmospheric pressure, obviating the need for a large, expensive containment dome and having little danger of explosion.
• LFTRs cannot melt down since the normal operating state is already molten.
• LFTRs are stable to rising temperatures since salt expands slowing the reaction. A salt plug kept solid by cooling coils will automatically melt if external power is lost and the fluid drain out to a safe dump tank.
• Salts used are solid below 300 F or higher, so any spilled fuel solidifies instead of escaping into the environment.
• Liquid fuels use almost all the available energy is used, unlike solid fuels that must be removed before they have generated 1-3 percent of the available energy because of damage.
• The radiative waste is much less than from conventional plants and far more manageable.
• Air-cooling possible where water is scarce.
• Should be cheaper than coal, especially if CO2 is sequestered.
• Proliferation resistant. Can't use to build bombs.
• Smaller size and lower cost.
• Could provide the world's energy needs carbon-free for a thousand years.
The gamma rays from U-232 are not a problem for reactors since unlike nuclear weapons they are already sufficiently shielded.
Of course, the disasters at Three-Mile-Island, Chernobyl, and Fukushima has greatly chilled public acceptance of nuclear power. But if these plants had used LFTRs, no radiation would have escaped to the environment.
Although far less of a problem than U-235 and Pu-239, waste from U-233 still has to be stored someplace. Here a comparison can be made with carbon sequestration in which waste CO2 is pumped into the ground, which is being talked about as a solution to problem of coal pollution. The amount of underground space needed to store a year's CO2 output from a single coal power plant is equivalent to 600 football fields filled to a height of ten yards. By comparison, one football field filled to the same height is required for all the waste from the entire civilian nuclear program.
Work on LFTR is going on worldwide, with research being done in China, France, the Czech Republic, Japan, Russia, Canada, and the Netherlands. The only significant U.S. research is on molten salt reactors, but with no emphasis on thorium. The U.S. may end up buying LFTRs from China. Perhaps WalMart will sell them cheap.
Thanks to reactor physicist Bob Zannelli for bringing LFTR to my attention and helping me learn the science.
Further Reading:
World Health Organization, "Air Quality and Health: Fact Sheet No. 313".
Daniel Yergin, The Quest: Energy, Security and the Remaking of the Modern World, (New York: Penguin Press, 2011).
Robert Hargraves, and Ralph Moir, "Liquid Fluoride Thorium Reactors: An Old Idea in Nuclear Power Gets Reexamined," American Scientist 98, no. 4(2010): 304-13.
Robert Hargraves, and Ralph Moir, "Liquid Fuel Nuclear Reactors," Physics & Society 40, no. 1(2011): 6-10.
Also, see the online lecture by Robert Hargraves "Aim High: Using Thorium to Address Environmental Problems".
Fluoride
From Wikipedia, the free encyclopedia
This article is about the fluoride ion. For a review of fluorine compounds,
| Fluoride | |||
|---|---|---|---|
|
|
|||
|
Fluoride[1]
|
|||
| Identifiers | |||
| CAS number | 16984-48-8 |
||
| PubChem | 28179 | ||
| ChemSpider | 26214 |
||
| KEGG | C00742 |
||
| MeSH | Fluoride | ||
| ChEBI | CHEBI:17051 | ||
| ChEMBL | CHEMBL1362 |
||
| Gmelin Reference | 14905 | ||
| Jmol-3D images | Image 1 | ||
| Properties | |||
| Molecular formula | F− | ||
| Molar mass | 18.9984032 g mol−1 | ||
| Thermochemistry | |||
| Std molar entropy S |
145.58 J/mol K (gaseous)[2] | ||
| Std enthalpy of formation ΔfH |
−333 kJ mol−1 | ||
| Related compounds | |||
| Other anions | |||
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | |||
| Infobox references | |||
Fluoride is the simplest unary fluorine anion, the other being the tentatively investigated trifluorate(2 F—F)(1-) anion. Its salts are important chemical reagents and industrial chemicals, mainly used in the production of hydrogen fluoride for fluorocarbons. Structurally, and to some extent chemically, the fluoride ion resembles the hydroxide ion. Fluoride ions occur on earth in several minerals, particularly fluorite, but are only present in trace quantities in water.
Contents
Nomenclature
The systematic name fluoride, the valid IUPAC name, is determined according to the additive nomenclature. However, the name fluoride is also used in compositional IUPAC nomenclature which does not take the nature of bonding involved. Examples of such naming are sulfur hexafluoride and beryllium fluoride, which contains no fluoride ions whatsoever.Fluoride is also used non-systematically, to describe compounds which releases hydrogen fluoride upon acidification, or a compound that otherwise incorporates fluorine in some form, such as methyl fluoride and fluorosilicic acid. Hydrogen fluoride is itself an example of a non-systematic name of this nature. However, it is also a trivial name, and the preferred IUPAC name for fluorane.
Occurrence
Many fluoride minerals are known, but of paramount commercial importance is fluorite.[3] It is composed of calcium fluoride, with small impurities. The soft, colorful mineral is found worldwide and is common.Seawater fluoride levels are usually in the range of 0.86 to 1.4 mg/L (McNeely et al. , 1979; Benefield et al.., 1982; Bewers, 1971; Warner et al., 1975; Thompson and Taylor, 1933; Dave, 1984; Barbaro et al., 1981),[4] mean 1.1 mg/L. For comparison, chloride concentration in seawater is about 19 mg/L. The low concentration of fluoride reflects the insolubility of the alkaline earth fluorides, e.g., CaF2.
Fluoride is found naturally in low concentration in drinking water and foods. Fresh water supplies generally contain between 0.01–0.3 ppm.[5][6] In some locations, the fresh water contains dangerously high levels of fluoride, leading to serious health problems.
Chemical properties
Basicity
Fluoride can act as a base. It can combine with a proton (H+):- F– + H+ → HF
In aqueous solution, fluoride has a pKb value of 10.8. It is therefore a weak base, and tends to remain as the fluoride ion rather than generating a substantial amount of hydrogen fluoride. That is, the following equilibrium favours the left-hand side in water:
- F– + H2O
HF + HO–
Structure
Counter-intuitively, unlike the lower halides, the variety of possible salts containing true fluoride ions is rather restricted. Most metal fluorides are highly polar, covalently bonded molecular networks instead of ionic lattices. All of the alkali metal fluorides, and most of the alkali earth metal fluorides are true salts. In such true salts, fluoride typically assumes the primitive or face-centred cubic motifs. Fluoride is also found with weakly coordinating counter cations, such as in ammonium fluoride, in which it assumes the close-packed hexagonal motif. Under aqueous conditions, fluoride exists as a trigonal pyramidal-shaped hydrated complex, namely [F(H2O)3]-. Fluoride has the smallest monatomic, crystal and effective, ionic radii: 199 and 133 pm, respectively.Inorganic Chemistry
Upon treatment with a standard acid, fluoride salts convert to hydrogen fluoride and metal salts. With strong acids, it can be doubly protonated to give H2F+. Oxidation of fluoride gives fluorine. Solutions of inorganic fluorides in water contain F− and bifluoride HF−
2.[7] Few inorganic fluorides are soluble in water without undergoing significant hydrolysis. In terms of its reactivity, fluoride differs significantly from chloride and other halides, and is more strongly solvated in protic solvents due to its smaller radius/charge ratio. Its closest chemical relative is hydroxide. When relatively unsolvated, for example in nonprotic solvents, fluoride anions are called "naked". Naked fluoride is a very strong Lewis base,[8] it is easily reacted with Lewis acids, forming strong adducts. Fluoride is susceptible to extreme ultraviolet radiation, ejecting an electron to become highly reactive atomic fluorine. It has a standard electrode potential of 2.87 Volts.
Biochemistry
At physiological pHs, hydrogen fluoride is usually fully ionised to fluoride. In biochemistry, fluoride and hydrogen fluoride are equivalent. Fluorine, in the form of fluoride, is considered to be a micronutrient for human health, necessary to prevent dental cavities, and to promote healthy bone growth.[5] The tea plant (Camellia sinensis L.) is a known accumulator of fluorine compounds, released upon forming infusions such as the common beverage. The fluorine compounds decompose into products including fluoride ions. Fluoride is the most bioavailable form of fluorine, and as such, tea is potentially a vehicle for fluoride dosing.[9] Approximately, fifty percent of absorbed fluoride is excreted renally with a twenty four hour period. The remainder can be retained in the oral cavity, and lower digestive tract. Fasting dramatically increases the rate of fluoride absorption to near hundred percent, from a sixty to eighty percent when taken with food.[9] Per a 2013 study, it was found that consumption of one litre of tea a day, can potentially supply the daily recommended intake of 4 mg per day. Some lower quality brands can supply up to a 120 percent of this amount. Fasting can increase this to 150 percent. The study indicates that tea drinking communities are at an increased risk of fluorosis, in the case where water fluoridation is in effect.[9] Fluoride ion in low doses in the mouth reduces tooth decay. For this reason, it is used in toothpaste and water fluoridation. At much higher doses, fluoride causes health complications and can be toxic.Applications
Fluoride salts and hydrofluoric acid are the main fluorides of industrial value. Compounds with C-F bonds fall into the realm of organofluorine chemistry. The main uses of fluoride, in terms of volume, are in the production of cryolite, Na3AlF6. It is used in aluminium smelting. Formerly, it was mined, but now it is derived from hydrogen fluoride. Fluorite is used on a large scale to separate slag in steel-making. Mined fluorite (CaF2) is a commodity chemical used in steel-making.Hydrofluoric acid and its anhydrous form, hydrogen fluoride, is also used in the production of fluorocarbons Hydrofluoric acid has a variety of specialized applications, including its ability to dissolve glass.[3]
Cavity prevention
Main articles: Fluoride therapy and Water fluoridation
Fluoride-containing compounds are used in topical and systemic fluoride therapy for preventing tooth decay. They are used for water fluoridation and in many products associated with oral hygiene.[10] Originally, sodium fluoride was used to fluoridate water; hexafluorosilicic acid (H2SiF6) and its salt sodium hexafluorosilicate (Na2SiF6) are more commonly used additives, especially in the United States. The fluoridation of water is known to prevent tooth decay[11][12] and is considered by the U.S. Centers for Disease Control and Prevention as "one of 10 great public health achievements of the 20th century".[13][14]
In some countries where large, centralized water systems are uncommon,
fluoride is delivered to the populace by fluoridating table salt. For
the method of action for cavity prevention (see Fluoride therapy). Fluoridation of water has its critics (see Water fluoridation controversy).[15]Biochemical reagent
Fluoride salts are commonly used in biological assay processing to inhibit the activity of phosphatases, such as serine/threonine phosphatases.[16] Fluoride mimics the nucleophilic hydroxide ion in these enzymes' active sites.[17] Beryllium fluoride and aluminium fluoride are also used as phosphatase inhibitors, since these compounds are structural mimics of the phosphate group and can act as analogues of the transition state of the reaction.[18][19]Estimated daily intake
Daily intakes of fluoride can vary significantly according to the various sources of exposure. Values ranging from 0.46 to 3.6–5.4 mg/day have been reported in several studies (IPCS, 1984).[20] In areas where water is fluoridated this can be expected to be a significant source of fluoride, however fluoride is also naturally present in huge range of foods, in a wide range of concentrations.[21] The maximum safe daily consumption of fluoride is 10mg for an adult.| Food/Drink | Fluoride (mg per 100g) |
Portion | Fluoride (mg per portion) |
|---|---|---|---|
| Black Tea (brewed) | 0.373 | 1 cup, 240g (8 fl oz) | 0.884 |
| Raisins, seedless | 0.234 | small box, 43g (1.5 oz) | 0.033 |
| Table wine | 0.153 | Bottle, 750ml (26.4 fl oz) | 1.150 |
| Municipal tap-water, (Fluoridated) |
0.081 | Recommended daily intake, 3 litres (0.79 US gal) |
2.433 |
| Baked potatoes, Russet | 0.045 | Medium potato, 140g (0.3 lb) | 0.078 |
| Lamb | 0.032 | Chop, 170g (6 oz) | 0.054 |
| Carrots | 0.003 | 1 large carrot, 72g (2.5 oz) | 0.002 |
Safety
Ingestion
Main article: Fluoride toxicity
According to the U.S. Department of Agriculture, the Dietary
Reference Intakes, which is the "highest level of daily nutrient intake
that is likely to pose no risk of adverse health effects" specify
10 mg/day for most people, corresponding to 10 L of fluoridated water
with no risk. For infants and young children the values are smaller,
ranging from 0.7 mg/d for infants to 2.2 mg/d.[22] Water and food sources of fluoride include community water fluoridation, seafood, and tea. [2]Soluble fluoride salts, of which sodium fluoride is the most common, are only mildly toxic, although they have resulted in both accidental and suicidal deaths from acute poisoning.[3] The lethal dose for most adult humans is estimated at 5 to 10 g (which is equivalent to 32 to 64 mg/kg elemental fluoride/kg body weight).[23][24][25] However, a case of a fatal poisoning of an adult with 4 grams of sodium fluoride is documented,[26] while a dose of 120 g sodium fluoride has been survived.[27] For Sodium fluorosilicate (Na2SiF6), the median lethal dose (LD50) orally in rats is 0.125 g/kg, corresponding to 12.5 g for a 100 kg adult.[28]
The fatal period ranges from 5 min to 12 hours.[26] The mechanism of toxicity involves the combination of the fluoride anion with the calcium ions in the blood to form insoluble calcium fluoride, resulting in hypocalcemia; calcium is indispensable for the function of the nervous system, and the condition can be fatal.
Treatment may involve oral administration of dilute calcium hydroxide or calcium chloride to prevent further absorption, and injection of calcium gluconate to increase the calcium levels in the blood.[26] Hydrogen fluoride is more dangerous than salts such as NaF because it is corrosive and volatile, and can result in fatal exposure through inhalation or upon contact with the skin; calcium gluconate gel is the usual antidote.[29]
In the higher doses used to treat osteoporosis, sodium fluoride can cause pain in the legs and incomplete stress fractures when the doses are too high; it also irritates the stomach, sometimes so severely as to cause ulcers. Slow-release and enteric-coated versions of sodium fluoride do not have gastric side effects in any significant way, and have milder and less frequent complications in the bones.[30] In the lower doses used for water fluoridation, the only clear adverse effect is dental fluorosis, which can alter the appearance of children's teeth during tooth development; this is mostly mild and is unlikely to represent any real effect on aesthetic appearance or on public health.[31] Fluoride was known to enhance the measurement of bone mineral density at the lumbar spine, but it was not effective for vertebral fractures and provoked more non vertebral fractures.[32]
In areas that have naturally occurring high levels of fluoride in groundwater both dental and skeletal fluorosis can be prevalent and severe.[33]
Topical
Concentrated fluoride solutions are corrosive. Gloves made of nitrile rubber, are worn when handling fluoride compounds. The hazards of solutions of fluoride salts depend on the concentration. In the presence of strong acids, fluoride salts release hydrogen fluoride, which is highly corrosive.Other derivatives
Organic and inorganic anions are produced from fluoride, including:- Bifluoride used as an etchant for glass.
- Tetrafluoroberyllate
- Hexafluoroplatinate
- Tetrafluoroborate used in organometallic synthesis.
- Hexafluorophosphate used as an electrolyte in commercial secondary batteries.
- Trifluoromethanesulfonate
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